Chemistry: Electrochemistry Flashcards
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Read the first 7 Chemistry: Electrochemistry flashcards as text
In an electrolytic cell, the source of energy driving the nonspontaneous reaction is:
Answer: An external power supply
Electrolytic cells require an external power source to drive nonspontaneous reactions.
How does the sign of the anode differ between galvanic and electrolytic cells?
Answer: Negative in galvanic, positive in electrolytic
The anode is negative in a galvanic cell but positive in an electrolytic cell.
Faraday's constant (about 96,485 C/mol) represents the charge of:
Answer: One mole of electrons
Faraday's constant is the total charge carried by one mole of electrons.
During electrolysis of molten NaCl, what forms at the cathode?
Answer: Sodium metal
Na⁺ ions are reduced to sodium metal at the cathode.
If 2.0 mol of electrons pass through a cell depositing a +2 metal, how many moles of metal are deposited?
Answer: 1.0 mol
Each metal ion requires 2 electrons, so 2.0 mol electrons deposit 1.0 mol of metal.
How much charge passes when a current of 5.0 A flows for 200 seconds?
Answer: 1000 C
Charge Q = I × t = 5.0 A × 200 s = 1000 C.
In the electrolysis of aqueous NaCl (brine), why is hydrogen often produced instead of sodium at the cathode?
Answer: Water is more easily reduced than Na⁺
Water has a more favorable reduction potential than Na⁺, so H₂ is produced preferentially.